Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(II)-azide-pyrazine (6,3) 2D net
Journal article, 2009
The methyl groups of [Cu2(2,5-dimethylpyrazine)(N3)4]n, 1, force penta-coordination on the Cu(II) ions, which, together with the di-μ1,1-azido zigzag chains, result in a (6,3) 2D net with dominant ferromagnetic interactions.
Coordination
X-ray structure analysis
magnetism
Author
Al-Shimaà A A Massoud
Chalmers, Chemical and Biological Engineering, Physical Chemistry
Morsy A.M. Abu-Youssef
Alexandria University
Jana Poltierova Vejpravova
Charles University in Prague
Vratislav Langer
Chalmers, Chemical and Biological Engineering, Environmental Inorganic Chemistry
Lars Öhrström
Chalmers, Chemical and Biological Engineering, Physical Chemistry
CrystEngComm
1466-8033 (ISSN)
Vol. 11 2 223-225Subject Categories (SSIF 2011)
Inorganic Chemistry
Condensed Matter Physics
DOI
10.1039/b815264k