Chirality Detection Using Nematic Liquid Crystal Droplets on Anisotropic Surfaces
Journal article, 2016
Nematic liquid crystals (NLCs) form helical macroscopic structures through chiral induction when doped with chiral species. We describe a very simple, though highly sensitive method for determination of handedness and pitch of the induced twist in the case of very weak twisting powers of such chiral dopants. A tiny drop typically less than 10 nL-of the chiral doped NLC is placed on a plate promoting a uniform planar surface anchoring of the liquid crystal director. At the curved NLC air interface the anchoring is homeotropic and in the sessile droplets we get a locally twisted hybrid director structure with a disclination line extending across the droplet. The configuration of the disclination line (S-like or backwards S-like) reveals the sign of twisting power and extremely large pitch values in the range of 10 mm can easily be measured. We demonstrate the method using the standard NLC 4-cyano-4'-pentylbiphenyl (5CB), weakly doped with the chiral material 2-hydroxy-2-phenylacetic acid (mandelic acid).
configuration
phases
v91
Chemistry
cholesteric pitch
helical twisting power
cell
Materials Science
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molecular chirality
1987
index
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polarization
berichte der bunsen-gesellschaft-physical chemistry chemical physics
v58
p599
egemeyer h
physical review a
v10
p1881
raley jp
model
naturwissenschaften
egemey.h
p3
Author
Per Rudquist
Chalmers, Microtechnology and Nanoscience (MC2), Photonics
C. F. Dietrich
Universitat Stuttgart
A. G. Mark
Max Planck Institute for Intelligent Systems
F. Giesselmann
Universitat Stuttgart
Langmuir
07437463 (ISSN) 15205827 (eISSN)
Vol. 32 24 6140-6147Subject Categories (SSIF 2011)
Materials Chemistry
DOI
10.1021/acs.langmuir.6b00382
PubMed
27244587