High-Entropy Mixtures of Pristine Fullerenes for Solution-Processed Transistors and Solar Cells
Journal article, 2015
The solubility of pristine fullerenes can be enhanced by mixing C60 and C70 due to the associated increase in configurational entropy. This "entropic dissolution" allows the preparation of field-effect transistors with an electron mobility of 1 cm2 V-1 s-1 and polymer solar cells with a highly reproducible power-conversion efficiency of 6%, as well as a thermally stable active layer.
configurational entropy
field-effect transistors
organic solar cells
solubility
fullerenes
Author
Amaia Diaz de Zerio Mendaza
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
A. Melianas
Linkopings universitet
Stephan Rossbauer
Imperial College London
Olof Bäcke
Chalmers, Applied Physics, Eva Olsson Group
Lars Nordstierna
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
Paul Erhart
Chalmers, Applied Physics, Materials and Surface Theory
Eva Olsson
Chalmers, Applied Physics, Eva Olsson Group
Thomas D. Anthopoulos
Imperial College London
Olle Inganaes
Chalmers University of Technology
Linkopings universitet
Christian Müller
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
Advanced Materials
09359648 (ISSN) 15214095 (eISSN)
Vol. 27 45 7325-7331Subject Categories (SSIF 2011)
Other Engineering and Technologies
Chemical Engineering
DOI
10.1002/adma.201503530